By using organizational cooperation as an intermediary variable, this study aimed to investigate the effects of principal's cross-border leadership on value creation. Questionnaire survey was used. The questionnaires were given to a random sample of educators (including principals, directors, section chiefs, homeroom teachers and subject teachers) across Taoyuan County, Hsinchu County and Miaoli County. The study used structural equation modeling to verify the linear relationship among cross-border leadership, organization cooperation and value creation. The results indicate that principal's cross-border leadership has a significant positive correlation with school organization and value creation. Principal's cross-border leadership also has a significant positive correlation with school value creation. Principals can implement cross-border leadership to help organization cooperation and to enhance school value creation. In addition, principal's cross-border leadership will indirectly influence value creation. The study suggested that principals implement cross-border leadership to enhance organization value creation and to create school value via organization cooperation.